Ana Industries P. LTd.

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Hydrogen Peroxide SDS, Safety Data Sheet or MSDS of Manufacturer Exporter, Uses Price Monograph

Hydrogen Peroxide Specifications of Manufacturer

Hydrogen Peroxide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

Section 1. Product Information

Product Name/Trade Name: Hydrogen Peroxide
CAS Number 7722-84-1
EINECS EC Number: 231-765-0
Chemical Formula: H2O2
Molecular Weight: 34.01
Relevant uses and uses advised against (if any): Industrial Manufacturing.

Section 2: Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910

Classification according to Regulation (EC) No 1272/2008
Oxidizing liquids; oxidizing solids Category 3, H272
Acute toxicity, oral Category 3, H301
Skin corrosion/irritation Category 1A, B, C H314
Acute toxicity (inhalation) Category 4, H332
Specific target organ toxicity - single exposure, Category 3, H335
Chronic aquatic toxicity (Category 3), H412

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements Aquatic Toxicity	GHS Label Elements Corrosive
GHS Label Elements Oxidizer	GHS Label Elements Toxic

Signal Words: Danger

Hazard statements:
H272 May intensify fire; oxidizer
H301 Toxic if swallowed.
H314 Causes severe skin burns and eye damage.
H332 Harmful if inhaled
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.

Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220: Keep/Store away from clothing/…/combustible materials.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P314: Get medical advice/attention if you feel unwell.
P301+310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container in accordance with local/regional/national/international regulation.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
O Oxidizing
C Corrosive
T Toxic
Risk Phrases:
R8 Contact with combustible material may cause fire
R25 Toxic if swallowed
R35 Causes severe burns
R41 Risk of serious damage to eyes.
Other Information: Keep container in a cool place out of direct sunlight. Store only in vented containers. Avoid storing on wooden pallets. Avoid contamination - Contamination could cause decomposition and generation of oxygen which may result in possible container rupture.

Section 3: Composition and Information on Ingredients

Product Name/Trade Name: Hydrogen Peroxide
CAS No.: 7722-84-1
EINECS EC Number: 231-765-0
Percentage: >30% and <70%

Section 4. First Aid & Procedure

Always get medical attention after the first aid is over.

Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin: Immediately flush skin with plenty of water for at least 15 minutes. Remove and wash contaminated clothing and shoes before reuse. Get medical attention if irritation develops.
Eyes: Immediately flush eyes with plenty of water for 15 minutes, occasionally lifting upper and lower eyelids. Hold eyelids apart during irrigation. Get medical attention.
Inhalation: Remove person to fresh air. If breathing is difficult, give oxygen. If not breathing administer artificial respiration. Get medical attention.
Hydrogen peroxide is a strong oxidant. Direct contact with the eye is likely to cause corneal damage especially if not washed immediately. Careful opthalmologic evaluation is recommended and the possibility of local corticosteroid therapy should be considered. Because of the likelihood of corrosive effects on the gastrointestinal tract after ingestion, and the unlikelihood of systemic effects, attempts at evacuating the stomach via emesis induction or gastric lavage should be avoided.

Section 5. Fire Fighting Measures

Flash Point: N/A
Fire/Explosion: The product is not combustible, but it is an oxidizer.
Extinguishing Medium: Water. Do not use any other substance.
Hazardous Combustion Products: On decomposition product releases oxygen which may intensify fire.
Fire Fighting Instructions: Use suitable protective equipment for surrounding fire.
In closed unventilated containers, risk of rupture due to the increased pressure from decomposition. Contact with combustible material may cause fire.

Section 6. Spills and Disposals

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Dike to collect large liquid spills. Stop leak and contain spill if this can be done safely. Pick up and arrange disposal without creating mist/dust. Sweep up and shovel. Keep in suitable, closed containers for disposal. Avoid mist formation. Avoid breathing vapors, dust/mist or gas. Ensure adequate ventilation. Don't touch or walk through this product. Stop leak if safe to do so. Prevent entry into waterways, drains, confined areas. Collect material and place it into loosely covered plastic containers for later disposal.
Combustible materials exposed to hydrogen peroxide should be immediately submerged in or rinsed with large amounts of water to ensure that all hydrogen peroxide is removed. Residual hydrogen peroxide that is allowed to dry (upon evaporation hydrogen peroxide can concentrate) on organic materials such as paper, fabrics, cotton, leather, wood or other combustibles can cause the material to ignite and result in fire.

Section 7. Handling and Storage

Toxic Hazardous material.
Precautions for safe handling: Avoid prolonged or repeated exposure. Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Keep/Store away from clothing/ combustible materials. Isolate from all combustibles and incompatible substances. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like organic materials, powdered metals, strong reducing agents. Hydrogen peroxide should be stored only in vented containers and transferred only in a prescribed manner.

Section 8. Exposure Controls & Personal Protection

Exposure Limits: ACGIH TLV: TWA: 1 ppm, OSHA PEL: TWA: 1 ppm & TWA: 1.4 mg/m3
Engineering Controls: Use adequate exhaust ventilation to keep airborne concentrations below the allowable exposure limit.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles.
Skin: Wear appropriate protective gloves.
Respiratory System: Approved or certified respirators.
Other Protective Equipment: Overalls or similar protective apparel, clean up facilities.
Don't eat, drink or smoke in work areas. Wash hands thoroughly after handling this material.
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

Section 9. Physical & Chemical Data

Appearance: Clear Colorless Liquid.
Odor: None
Odor threshold: Not available.
pH: Varies with assay
Specific Gravity: Varies with assay
Melting Point: Varies with assay
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Miscible in water.
Viscosity: Not available.
Chemical Formula: H2O2
Molecular Weight: 34.01

Section 10. Stability and Reactivity

Chemical Stability: Stable under recommended temperatures and pressures. It is an oxidizer.
Incompatibility (Materials to Avoid): Organic materials, Powdered metals, Strong reducing agents.
Conditions to Avoid: Incompatible materials, excessive heat and light.
Hazardous Decomposition Products: Oxygen that supports combustion.
Hazardous Polymerization: Will not occur.

Section 11. Toxicological Information

Toxicity to Animals:
LD50 Oral 50% solution: LD50 > 225 mg/kg bw (rat)
LD50 Oral 35 % solution:LD50 1193 mg/kg bw (rat)
LD50 Oral 70 % solution: LD50 1026 mg/kg bw (rat)
Carcinogenicity: IARC: 3- Group 3: Not classifiable as to its carcinogenicity to humans (Hydrogen peroxide).

Section 12. Ecological Information

Ecotoxicity: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Toxicity to fish: LC50 semi-static test Pimephales promelas: 16.4 mg/l / 96 h.
Toxicity to daphnia and other aquatic invertebrates: EC50 semi-static test Daphnia pulex: 2.4 mg/l / 48 h
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Mobility: Expected to be mobile.

Section 13. Disposal Suggestions

Dispose of in accordance with all applicable local, state and federal regulations at an approved waste disposal facility.

Section 14. Transport and Label Information

DOT (USA) & ADR/RID:
UN number: 2014 Class: 5.1 (8) Packing group: II
Proper shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
IMDG/IMO
UN number: 2014 Class: 5.1 (8) Packing group: II
Proper shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION
IATA:
UN number: 2014 Class: 5.1 (8) Packing group: II
Proper shipping name: HYDROGEN PEROXIDE, AQUEOUS SOLUTION

Section 15. Regulatory Information

USA:
SARA 302: Listed.
SARA 313 Components: Not listed.
SARA 311/312: Hazardous Categorization: Acute Health Hazard; Fire Hazard.
California Prop.65: Not listed.

Section 16. Other Information

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Contact Hydrogen Peroxide Manufacturers Suppliers Exporters:

Ana Industries P. LTd.
email: info@anaindustries.org
Call: +912223774610
Houston USA, Dubai UAE Dahej & Mumbai India.