Ana Industries P. LTd. Sodium Metaperiodate SDS, Safety Data Sheet or MSDS of Manufacturer Exporter
Sodium Metaperiodate Specifications of Manufacturer
Sodium Metaperiodate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet1. Product Identification
Product Name & Other Names: Sodium Metaperiodate
CAS Number 7790-28-5
EINECS: EC Number: 232-197-6
Molecular Weight: 213.89
Chemical Formula: NaIO4
Relevant uses and uses advised against (if any): Industrial Manufacturing
SUPPLIER: As per Letterhead.2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Oxidizing liquids; Oxidizing solids Category 1 - H271
Skin corrosion/irritation Category 1A, B, C - H314
Specific target organ toxicity - repeated exposure Category 1, thymus gland, H372
Short-term (acute) aquatic hazard Category 1, H400Labeling according Regulation (EC) No 1272/2008
GHS Label Elements
Oxidizing Solid GHS Label Elements
Corrosive GHS Label Elements
Health Hazard GHS Label Elements
Marine PollutantSignal Word: Danger
Hazard Statements:
H271: May cause fire or explosion; strong oxidizer.
H314: Causes severe skin burns and eye damage.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.Precautionary Statements:
P201: Obtain special instructions before use.
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P263: Avoid contact during pregnancy/while nursing.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+330+331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+361+353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306 + P360: IF ON CLOTHING: rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P371 + P380 + P375: In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
P308+313: IF exposed or concerned: Get medical advice/attention.
P362: Take off contaminated clothing and wash before reuse.
P337+P313 If eye irritation persists: Get medical advice/ attention.
P391: Collect spillage.
P405: Store locked up.
P501: Dispose of contents/container to authorized agents only.Classification according to EU Directives 67/548/EEC or 1999/45/EC
Hazard Symbols:
O Oxidizing R 8
C Corrosive R34
T Toxic R48/25
N Dangerous for the environment R50
Risk Phrases:
R 8 Contact with combustible material may cause fire.
R34 Causes burns.
R 41 Risk of serious damage to eyes.
R48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed.
R50 Very toxic to aquatic organisms.
R 36/37/38 Irritating to eyes, respiratory system and skin.3. Composition/Information on Ingredients
Product: Sodium Metaperiodate
CAS No.: 7790-28-5
EINECS: EC Number: 232-197-64. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.5. Fire Fighting Measures
Flammability of the Product: Non-flammable but it is an oxidizer.
Auto-Ignition Temperature: Not applicable.
Products of Combustion: It emits toxic iodine, hydrogen iodide, sodium oxide and oxygen when heated to decomposition.
Fire: It is supporting fire as an oxidizer.
Explosion: Contact with oxidizable substances may cause explosion.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Use means suitable for extinguishing surrounding fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Contain spilled material. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as required by law.7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like organic substances, metal powders reducing agents and combustible substances. The item is hygroscopic and light sensitive.8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.9. Physical and Chemical Properties
Appearance: White to off-white crystalline powder or granules.
Odor: None.
Odor threshold: Not available.
pH: 5.2 at 20 g/l at 20C
Relative Density: 3.86
Melting Point: 300C Decomposes.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Decomposition Temperature: 270C
Auto-ignition temperature: 262C
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Weight: 213.89
Chemical Formula: NaIO4
Oxidizing Properties: The substance or mixture is classified as oxidizing category 1.10. Stability and Reactivity
Stability: It is stable under recommended conditions of use and storage. Violent reactions possible with: combustible substances, ammonium compounds, perchlorates, Powdered metals, Reducing agents, acids, magnesium.
Hazardous Decomposition Products: It emits toxic iodine, hydrogen iodide, sodium oxide and oxygen when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic substances, Metal powders and Reducing agents.
Conditions to Avoid: Incompatibles moisture, light and heat.11. Toxicological Information
Toxicity to Animals:
LD50 Intraperitoneal - Mouse - 58 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as probable or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.12. Ecological Information
Toxicity to fish: semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - > 0,17 mg/l - 96 h.
Toxicity to daphnia and other aquatic invertebrates: static test EC50 - Daphnia magna (Water flea) - 0,18 mg/l - 48 h.
Persistence and degradability: Not available.
Bioaccumulative potential: Not available.
Mobility in soil: Not available.
Results of PBT and vPvB assessment: Not available.
Very toxic to aquatic life.13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.
14. Transport Information
DOT (USA)
UN number: 3085 Class: 5.1 (8) Packing group: I
Proper shipping name: OXIDIZING SOLID, CORROSIVE, N.O.S. Periodic acid (HIO4), sodium salt.
IMDG
UN number: 3085 Class: 5.1 (8) Packing group: I
Proper shipping name: OXIDIZING SOLID, CORROSIVE, N.O.S. Periodic acid (HIO4), sodium salt.
IATA
UN number: 3085 Class: 5.1 (8) Packing group: I
Proper shipping name: OXIDIZING SOLID, CORROSIVE, N.O.S. Periodic acid (HIO4), sodium salt.15. Regulatory Information
USA:
SARA 302 Components: Not applicable.
Section 313: Not applicable.
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard, Reactivity Hazard.
California Proposition 65: This product does not contain any Proposition 65 chemicalsSection 16 - Additional Information
H271: May cause fire or explosion; strong oxidizer.
H314: Causes severe skin burns and eye damage.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.Hazard Symbols:
O Oxidizing R 8
C Corrosive R34
T Toxic R48/25
N Dangerous for the environment R50
Risk Phrases:
R 8 Contact with combustible material may cause fire.
R34 Causes burns.
R 41 Risk of serious damage to eyes.
R48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed.
R50 Very toxic to aquatic organisms.
R 36/37/38 Irritating to eyes, respiratory system and skin.DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Contact Sodium Metaperiodate Manufacturers Suppliers Exporters:
Ana Industries P. LTd.
email: info@anaindustries.org
Call: +912223774610
Houston USA, Dubai UAE Dahej & Mumbai India.