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Ana Industries P. LTd. |
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Stable Sodium Perborate Monohydrate SDS, Safety Data Sheet or MSDS of Manufacturer Exporter
Sodium Perborate Specifications of Manufacturer
Sodium Perborate Monohydrate Anhydrous SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
1. Product Identification
Product Name & Other Names: Sodium Perborate.
CAS No.: 10332-33-9 Monohydrate), 7632-04-4 or 11138-47-9 (Anhydrous)
EINECS: EC Number: 231-556-4 or 234-390-0 (Anhydrous, Monohydrate)
Molecular Weight: 81.82 Anhydrous, 99.81 Monohydrate
Chemical Formula: BNaO3 Anhydrous, BNaO3.H2O Monohydrate
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Oxidizing solids Category 3, (H272)
Reproductive toxicity Category 1B, (H360)
Acute toxicity, Oral Category 4, (H302)
Specific target organ toxicity - single exposure Category 3, (H335)
Serious eye damage Category 1, (H318)
Labelling according Regulation (EC) No 1272/2008
| GHS Label Elements  Oxidizing Solid |
GHS Label Elements |
GHS Label Elements |
GHS Label Elements |
Signal word: Danger
Hazard statement(s):
H272 May intensify fire; oxidizer.
H302 Harmful if swallowed.
H318 Causes serious eye damage.
H331 Toxic if inhaled.
H335 May cause respiratory irritation.
H360 May damage fertility or the unborn child.
Precautionary statement(s):
P201 Obtain special instructions before use.
P202: Do not handle until all safety precautions have been read and understood.
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P220 Keep/Store away from clothing/ combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P264: Wash … thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/ eye protection/ face protection.
P330: Rinse mouth.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P370+378: In case of fire: Use Water spray, Foam for extinction.
P301+312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P308+313: IF exposed or concerned: Get medical advice/attention.
P405: Store locked up.
P403+233: Store in a well-ventilated place. Keep container tightly closed.
P501: Dispose of contents/container to an authorized agent only.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC:
Hazard Symbols:
T = Toxic
O = Oxidizing
Xn = Harmful
Xi = Irritant
Risk Phrases:
R61-23: May cause harm to the unborn child. Toxic by inhalation.
R62-22: Possible risk of impaired fertility. Harmful if swallowed.
R37-41 = Irritating to respiratory system. Risk of serious damage to eyes.
R8 = Contact with combustible material may cause fire.
3. Composition/Information on Ingredients
Ingredient: Sodium Perborate Monohydrate
CAS No.: 10332-33-9 (Monohydrate)
EINECS: EC Number: 231-556-4
Percent: 95 - 100%
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Symptomatic and supportive treatment is recommended.
5. Fire Fighting Measures
Flammability of the Product: Non-flammable but it is an oxidizer.
Auto-Ignition Temperature: Not applicable.
Products of Combustion: It emits toxic oxides of boron, sodium and fumes when heated to decomposition.
Fire: Sodium Perborate is supporting fire as an oxidizer.
Explosion: Contact with oxidizable substances may cause explosion.
Fire Extinguishing Media: Water spray, Foam. Use means suitable for extinguishing surrounding fire. Avoid carbon dioxide and gas filled extinguisher.
Special Information: Sodium Perborate is an oxidizer. In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures or when moistened under fire conditions, it may produce toxic or irritating fumes.
6. Accidental Release Measures
Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Avoid dust formation. Avoid breathing dust. Ensure adequate ventilation. Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.
Large Spill: Eliminate all sources of ignition. Do not let the product enter drains. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow evacuating as per law.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Wear suitable protective clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool <32C, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like combustible substances, Organic substances, reducing agents, powdered metals, strong bases, alcohols, phosphorous, anhydrides, halogens, acids, metal powders.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established. Limit.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Dust deposits on floors and other surfaces may pick up moisture and cause the surfaces to become slippery and present safety hazards. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: White crystals or powder.
Odor: None.
Odor threshold: Not available.
pH: 10 at 1% solution at 25 C (77F)
Relative density: 2.4 - 2.6
Melting Point: Decomposes at 60C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility: Soluble in water.
Viscosity: Not available.
Molecular Weight: 99.81
Molecular Formula: BNaO3- H2O
% Volatile by volume @ 21C (70F): 0
10. Stability and Reactivity
Stability: Sodium Perborate is stable under ordinary conditions of use and storage. It becomes unstable by heat and moisture.
Hazardous Decomposition Products: Oxygen, oxides of sodium, boron oxides and fumes.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic substances, Strong reducing agents, Powdered metals, Strong bases, Alcohols, phosphorous, Anhydrides, Halogens, Acids, Metal powders and Reducing agents.
Conditions to Avoid: Moisture, Heat, Incompatibles.
11. Toxicological Information
Toxicity to Animals:
ORAL (LD50): 1908 mg/kg (Rat).
ORAL (LD50): 1060 mg/kg [Mouse].
Intravenous (LD50 ): 600 mg/kg (Cat)
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.
Chronic Effects on Humans: May cause damage to the following organs: lungs, blood, mucous membranes.
Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.
12. Ecological Information
Environmental Toxicity:
LC50/96h: 51 mg/l (Brachydanio rerio)
NOEC/48h: 8 mg/l (Daphnia magna)
NOEC/96h: 25 mg/l (Brachydanio rerio).
Results of PBT and vPvB assessment: This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Small amounts of this material may be suitable for sanitary sewer or trash disposal.
14. Transport Information
DOT (USA)
Shipping Name: SODIUM PERBORATE MONOHYDRATE
Hazard Class: 5.1; Packing Group: III; Hazard Label: Oxidizer
UN Number: UN3377
IMDG
Shipping Name: SODIUM PERBORATE MONOHYDRATE
Hazard Class: 5.1; Packing Group: III; Hazard Label: Oxidizer
UN Number: UN3377
Marine pollutant: No
IATA
Shipping Name: SODIUM PERBORATE MONOHYDRATE
Hazard Class: 5.1; Packing Group: III; Hazard Label: Oxidizer
UN Number: UN3377
15. Regulatory Information
USA:
SARA 302: No chemicals in this material are subject to the reporting.
Section 313: No chemicals are reportable under Section 313.
SARA 311/312 Hazards: Fire Hazard, Immediate (Acute) Health Hazard.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. Other Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Contact Sodium Perborate Monohydrate Pure and BP Grade Manufacturers Suppliers Exporters:
Ana Industries P. LTd.
email: info@anaindustries.org
Call:
+912223774610
Houston USA, Dubai UAE Dahej & Mumbai India.