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Zinc Peroxide or Zinc Superoxide SDS, Safety Data Sheet or MSDS of Manufacturer Exporter, Uses Price Monograph

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Zinc Peroxide Manufacturer

Zinc Peroxide or Zinc Superoxide Specifications of Manufacturer

Zinc Peroxide SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet

1. Product Identification

Product Name & Other Names: Zinc Peroxide, Zinc Superoxide.
CAS Number 1314-22-3
Molecular Weight: 97.4
Chemical Formula: ZnO2
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910

Classification according to Regulation (EC) No 1272/2008
Oxidizing liquids; Oxidizing solids Category 1
Hazardous to the aquatic environment, acute hazard Category 3
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2A
Chronic aquatic toxicity Category 1

Labeling according GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Oxidizing Solid
Oxidizing Solid
GHS Label Elements
Irritant
Irritant
GHS Label Elements
marinepollutant.png
Aquatic Toxicity

Signal Word: Warning

Hazard Statements:
H271: May cause fire or explosion; strong oxidizer.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H410: Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P210: Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P273: Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P283: Wear fire/flame resistant/retardant clothing.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P306+360: IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P370+378: In case of fire: Use Dry chemical, carbon dioxide, Halon, water spray, or fog for extinction. If water is used, apply from as far a distance as possible.
P371+380+375: In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion.
P362: Take off contaminated clothing and wash before reuse.
P391: Collect spillage.
P501: Dispose of contents/container in accordance with local/regional/national/international regulations.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbols:
O Oxidizing
Xi Irritant
Risk Phrases:
R8 Contact with combustible material may cause fire
R36/38 Irritating to eyes and skin
R53 May cause long-term adverse effects in the aquatic environment

3. Composition/Information on Ingredients

Product: Zinc Peroxide, Zinc Superoxide.
CAS No.: 1314-22-3
Molecular Weight: 97.4
Chemical Formula: ZnO2

4. First Aid Measures

Always seek medical attention after first aid measures are provided.

Inhalation: If is inhaled, remove to fresh air. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing.
Skin Contact: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention.

5. Fire Fighting Measures

Fire: Substance is a strong oxidizer and its heat of reaction with reducing agents or combustibles may cause ignition.
Explosion: May explode when shocked, exposed to heat or flame, or by spontaneous chemical reaction. Sealed containers may rupture when heated. Sensitive to mechanical impact.
Fire Extinguishing Media: Dry chemical, carbon dioxide, Halon, water spray, or fog. Water spray may be used to keep fire exposed containers cool. Do not allow water runoff to enter sewers or waterways.
Special Information: Wear full protective clothing and breathing equipment for high-intensity fire or potential explosion conditions. This oxidizing material can increase the flammability of adjacent combustible materials.

6. Accidental Release Measures

Personal precautions, protective equipment and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spills.
Environmental precautions: Do not let the product enter drains, soil or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat or smoke while handling. Avoid contact with skin, eyes and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like organic compounds, carbonaceous materials, reducing agents, moisture, heat, light, combustibles or other readily oxidizable materials. Containers of may be hazardous when empty since they retain product residues (dust, solids).

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: TWA 2.0 mg/m3 USA, ACGIH Threshold Limit Values (TLV).
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance: Light yellow powder or granules.
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.57
Melting Point: 212C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: Not available.
Decomposition temperature: Not available.
Upper/lower flammability or explosive limits: Not available.
Vapor pressure: Not available.
Vapor density: Not available.
Evaporation rate: Not available.
Flammability (solid, gas): Not available.
Partition coefficient: n-octanol/water: Not available.
Solubility(ies): Not available.
Viscosity: Not available.

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Oxides of zinc, fumes may form when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Organic compounds, carbonaceous materials, reducing agents, moisture, heat, light, and many other substances.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.

11. Toxicological Information

Oral rat LD50: Not available.
Carcinogenicity: This product is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.
Mutagenic Effects: Not available.
Teratogenic Effects: Not available.
Developmental Toxicity: Not available.

12. Ecological Information

Toxicity: No data available
Persistence and degradability: No data available
Bioaccumulative potential: No data available
Mobility in soil: No data available

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing use or contamination of this product may change the waste management options. Dispose of container and unused contents in accordance legal requirements.

14. Transport Information

Domestic (Land, D.O.T.)
Proper Shipping Name: Zinc Peroxide
Hazard Class: 5.1, Packing Group: II
UN/NA: UN1516
International (Water, I.M.O.)
Proper Shipping Name: Zinc Peroxide
Hazard Class: 5.1, Packing Group: II
UN/NA: UN1516
International (Air, I.C.A.O.)
Proper Shipping Name: Zinc Peroxide
Hazard Class: 5.1, Packing Group: II
UN/NA: UN1516

15. Regulatory Information

USA:
SARA 302: No
SARA 313: Yes
SARA 311/312: Reactivity Hazard, Acute Health Hazard
California Prop. 65 Components: Not listed

Section 16 - Additional Information

H271: May cause fire or explosion; strong oxidizer.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H410: Very toxic to aquatic life with long lasting effects.
O Oxidizing
Xi Irritant
R8 Contact with combustible material may cause fire
R53 May cause long-term adverse effects in the aquatic environment
R36/38 Irritating to eyes and skin.

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

 

Contact Zinc Peroxide Manufacturers Suppliers Exporters:

Ana Industries P. LTd.
email: info@anaindustries.org
Call: +912223774610
Houston USA, Dubai UAE Dahej & Mumbai India.